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Frothers and Froth Stability Patents: Who Leads, Where Gaps Are 2026

Frothers and Froth Stability Patents: Who Leads, Where Gaps Are 2026
https://www.patsnap.com/resources/blog/rd-blog/frothers-and-froth-stability-patent-landscape/ · Patsnap · data cut-off 2026-07-31 · downloaded from the live page
Flotation & Reagents · Patent Landscape
Frothers and Froth Stability Patents: Mapping Who Files and Where Claims Concentrate
  • Concentration at the top. the five most active assignees hold 40.7% of all 172 records in scope, and the ranked leaders extend to 62 companies with a long tail beyond them.
  • Filing has cooled from its peak. 2021 to 2024 fell 90%, from 10 to 1 filing, after a peak of 18 in 2023 — though 2025-2026 figures are still filling in as publication catches up.
  • Flotation dominates the claim map. B03D covers 62.2% of records, while adjacent classes like polymer condensation (C08G, 6.4%) and polymer compositions (C08L, 6.4%) sit far thinner.
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172
Published Records
41%
Top-5 Share of All Records
-90%
Filing Growth 2021→2024
US
Leading Jurisdiction

Filing growth compares 2021 (10 records) with 2024 (1) — a three-year span. 2024 is the most recent year we treat as complete: publication lags filing by roughly 18 months, so 2025 onwards are still filling in and any growth rate that ends there would understate the field. Top-5 share is the combined record count of the five largest assignees divided by all 172 records in scope (CR5), not by the ranked leaders only.

Published byPatsnap Research··7 min readSourced from Patsnap Eureka
Overview

What this landscape covers

Frothers control bubble size and froth stability in mineral flotation, and the claim space spans reagent chemistry, froth-depth control and water-recovery management. This landscape draws on 172 published records filed or published between 2015 and mid-2026, searched against terms spanning frother chemistry (polyglycol frother, frother blend) and froth-behaviour metrics (critical coalescence concentration, water recovery, entrainment of fines, froth washing).

The dataset mixes chemical-composition claims with process-control claims, which is why flotation apparatus classes and polymer chemistry classes both appear prominently. Filing offices split across the United States, WIPO/PCT, Australia, Canada, Europe and Chile, reflecting the geography of active mining operations rather than a single dominant jurisdiction.

Records by filing year, 2015-2026
  1. 1HUNTSMAN AUSTRALIA24
  2. 2PRAXAIR TECH INC19
  3. 33M INNOVATIVE PROPERTIES CO9
  4. 4IP2IPO INNOVATIONS LTD9
  5. 5BASF SE9
  6. 6A N T TRUST8
  7. 7SUPAFLO TECH8
  8. 8STELLENBOSCH UNIVERSITY7
  9. 9AALTO UNIV FOUND7
  10. 10SOLVAY SA6
Source: Patsnap Eureka. Assignee ranking and totals. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP

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The Numbers

Filing trend and technology composition

Two views of the same 172 records: how filing activity moved year over year, and which IPC subclasses the claims actually sit in.

A sharp pullback from the 2023 peak

Filings rose to a peak of 18 in 2023 before falling to 1 in 2024, a -90% move from the 10 filings recorded in 2021. Because publication lags filing by roughly 18 months, 2025 and 2026 counts are still incomplete and should not yet be read as a continued decline.

A sharp pullback from the 2023 peak0510152002017201820192020202120221820232024202512026Most recent year is partial — publication lag means later filings are not yet visible.

Flotation apparatus claims dominate

B03D (flotation) appears in 62.2% of the 172 records, far ahead of any other class. Grinding and abrasive classes (B24B, B24D) each cover 11.6%, water treatment 9.9%, and polymer-chemistry classes cluster in the 6-16% range — records commonly carry more than one class, so these shares sum to well over 100%.

Flotation apparatus claims dominateB03D · Flotation10762.2%C07C · Acyclic & carbocyclic compounds2816.3%B24B · Grinding & polishing2011.6%B24D · Grinding tools & abrasives2011.6%C02F · Water & wastewater treatment179.9%C08J · Polymer processing & solutions127.0%C08G · Condensation polymers116.4%C08L · Polymer compositions116.4%Other5330.8%

Shares are the percentage of the 172 records in scope. A patent can carry several IPC classes, so the shares add up to more than 100%.

Source: Patsnap Eureka. Filing trend and technology composition. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.

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Key Patents

Representative and most-cited filings

Representative Filing
US20130299394A12013-11-14

Method and apparatus for froth flotation control (US20130299394A1)

IMPERIAL INNOVATIONS LIMITED

The invention provides a method of controlling operation of a froth flotation cell, the method comprising: introducing gas into a liquid in the cell, thereby to create a froth on the surface of the liquid, the froth having a depth from the surface of the liquid to an overflow point at which the froth overflows and leaves the cell; and controlling the froth depth to optimise the gas recovery with respect to the froth depth. Optimisation of the gas recovery with respect to the froth depth leads to the recovery of a froth concentrate of both high grade and high product recovery.Filed by Imperial Innovations Limited, published 2013-11-14.

US20130299394A1 — patent drawing 1US20130299394A1 — patent drawing 2
View full filing
Most-cited records in this landscape
#Publication no.Patent titleCitations
1US6121336ASurfactants for incorporating silica aerogel in polyurethane foams90
2US6903173B2Fluorinated polymers35
3US20040023016A1Fluorinated polymers34
4US20030231995A1Use of ozone to increase the flotation efficiency of sulfide minerals31
5US20090062414A1System and method for producing damping polyurethane CMP pads30
6US5746910AFrothless flotation apparatus29
7US2261439APreparation of cellular compositions of rubber or rubberlike substances26
8US20130140218A1Froth flotation and apparatus for same24
9US4804460AColumn flotation24
10US7152741B2Use of ozone to increase the flotation efficiency of sulfide minerals23

Citation counts favour older filings simply because they have had more time to be cited; treat them as a signal of influence within this corpus, not as a ranking of current relevance.

Each row carries its publication number; clicking a row searches Eureka by that number.

Source: Patsnap Eureka. Citation counts and representative records. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
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Insights

What the numbers mean for a filing decision

Three patterns worth acting on before drafting new claims in this space.

Concentration
40.7% of 172 records
held by the top 5 assignees

The top of the field is genuinely concentrated

Five assignees hold 40.7% of all 172 records, and the top 10 extend that to 61.6%. That leaves a long tail across the remaining ranked leaders, many with only one or two filings — a sign that late entrants are still finding room outside the core claim clusters.

Based on the 62-company assignee ranking
Momentum
-90% (2021→2024)
filings, most recent complete years

Activity has pulled back sharply from its 2023 peak

Filings peaked at 18 in 2023, then fell to 1 by 2024 — a 90% drop from the 10 filings recorded in 2021. Because publication lags filing by around 18 months, the 2025-2026 numbers are not yet reliable evidence of a continued slide.

2024 is the most recent complete filing year
Composition
62.2% B03D
of records classed under flotation

Apparatus and process claims outweigh chemistry claims

B03D (flotation) covers 62.2% of the 172 records, while the polymer-chemistry classes that describe frother compounds themselves (C08G, C08L) each sit at 6.4%. That imbalance suggests process-control and froth-behaviour claims are more heavily staked out than novel frother chemistries.

Classes overlap; shares sum above 100%
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Eureka can read the same corpus for gaps instead of for coverage: under-claimed branches adjacent to frothers and froth stability, with the prior art for and against each one.

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Source: Patsnap Eureka. Co-assignee relationships and derived observations. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
Players

Who is filing, and where the gaps sit

The ranked leaders span chemicals majors, mining-technology specialists and university research groups, but recent-year momentum has gone flat across the names with the largest historical portfolios.

Leader
24 records
the single largest filer in this ranking

One assignee holds a clear lead

The top-ranked assignee holds 24 records, well ahead of the fifth-place holder at 9 and the tenth-place holder at 6. That gap between first and fifth is the steepest part of the curve.

Out of 62 ranked companies
Momentum
0 in the latest year
across several top-10 assignees

Recent-year filing has gone quiet at the top

Several of the most active historical filers, including large chemicals and mining-technology names, show zero filings in the latest year, with one recording a -100% year-on-year change. This is consistent with the broader 2021-2024 pullback rather than a company-specific retreat.

Publication lag means the latest year is understated
Collaboration
10 co-assignee pairs
identified across the dataset

Co-filing is limited and mostly inventor-linked

Only 10 co-assignee pairings appear across the 172 records, and the strongest repeat pairs link a single corporate assignee to individual named inventors rather than to other companies. Cross-company joint filing is not a notable feature of this landscape.

Strongest pairs repeat twice each
🔍
Under-claimed branches worth checking before drafting
These sub-areas sit outside the dense B03D and C07C clusters and carry comparatively thin coverage in this dataset.
Frother blend synergy at low CCCFroth washing water-recovery controlEntrainment-of-fines suppression additivesPolyglycol frother biodegradability claimsSurface-tension real-time monitoring
Rank all filers by momentum →
Recent-year filing momentum by assignee
AssigneeRecent yearYoY
Huntsman Australia0
Praxair Technology, Inc.0
Solvay SA0
BASF SE0-100%
3M Innovative Properties Co.0
IP2IPO Innovations Ltd.0
A N T TRUST0-100%
Aalto University Foundation0
Source: Patsnap Eureka. Assignee-level momentum. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
What's Next

Where to take this analysis

The landscape points to a field with a settled apparatus-claim core and thinner coverage in chemistry and monitoring. Two directions follow from that.

Check the white-space chips against your own formulation

The under-claimed branches above are candidates for freedom-to-operate checks, not confirmed gaps — run a targeted search against your specific frother chemistry or froth-control method before committing claim language.

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Watch for the 2025-2026 filings still arriving

Because publication lags filing by about 18 months, the apparent 2024 drop-off is not the final word. Re-run this landscape in a future cycle before treating current filing levels as settled.

Set up monitoring in Patsnap Eureka
Source: Patsnap Eureka. Forward-looking reading of the same dataset. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
FAQ

Common questions about frother and froth stability patents

Answers are grounded in the same dataset. Derived from a Patsnap search on Frothers and Froth Stability covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP

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Disclaimer. This page is generated from Patsnap Eureka data drawn from a limited snapshot of global patent and scientific-literature records, and is provided for general information and reference only.

Patent data carries inherent limitations: recent filings (typically the most recent 18–24 months) are under-counted due to standard publication lag; counts may be reported at either a patent-family or a patent-record basis and are not always directly comparable; classification, applicant-name, and citation data may contain errors, duplicates, or omissions; and the underlying search query defines and constrains the scope shown. As a result, the analysis may be incomplete or inaccurate and may not reflect the full technology landscape.

Nothing on this page constitutes an exhaustive prior-art, novelty, freedom-to-operate, or validity search, nor does it constitute legal, financial, investment, or professional advice, and it should not be relied upon as such. Any patent, commercial, or strategic decision should be verified independently and reviewed with qualified patent, legal, and domain professionals. Patsnap makes no warranties, express or implied, as to the accuracy, completeness, or fitness for any particular purpose of the information presented.

Machine translation. Assignee and organisation names originally recorded in Chinese, Japanese or Korean have been rendered into English by an AI translation step so that the tables stay readable. These renderings are best-effort and may not match a company’s registered English name; the original name is what the underlying patent record carries, and it is what any Eureka query launched from this page uses.

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