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Run your analysis now →Filing growth compares 2021 (7 records) with 2024 (12) — a three-year span. 2024 is the most recent year we treat as complete: publication lags filing by roughly 18 months, so 2025 onwards are still filling in and any growth rate that ends there would understate the field. Top-5 share is the combined record count of the five largest assignees divided by all 154 records in scope (CR5), not by the ranked leaders only.
Low-GWP refrigerant patenting sits at the intersection of three older disciplines: refrigerant chemistry (C09K5), mechanical refrigeration system design (F25B9, F25B1), and lubricant formulation for the resulting working fluids. The search set of 154 patent families spans 2015 through the 2026 cut-off and clusters heavily around drop-in replacement claims, flammability classification, and system efficiency under new refrigerant blends rather than around novel refrigerant molecules themselves.
The filing curve rose to a peak of 43 records in 2018, coinciding with the compliance pressure created by phase-down schedules for high-GWP HFCs, then declined through the following years. Publication lag of roughly 18 months means the final year or two of any such trend always understates true filing activity, but the multi-year decline visible well before the cut-off is unlikely to be a lag artefact alone.
Two views of the same 154-family dataset: how filing activity has moved year over year, and how it splits across the IPC subclasses that define the technical scope of a low-GWP refrigerant claim.
From 2 records in 2017 to a peak of 43 in 2018, filings dropped back toward single digits by the 2022 midpoint. Read the final one to two years as directionally incomplete rather than as evidence of renewed decline, given publication lag.
C09K (materials, 112 records) and F25B (refrigeration and heat pump systems, 75) anchor the dataset. C10M and C10N together (50 records) show lubricant compatibility is a persistent secondary claim axis, while B60H (21) marks a distinct vehicle-specific sub-market and F24F, F25D and F04B remain thin at single-digit-to-low-double-digit counts.
Shares are the percentage of the 154 records in scope. A patent can carry several IPC classes, so the shares add up to more than 100%.
This page is one run against one query. Ask Eureka your own question about low-gwp refrigerants and every answer comes back with the patent numbers behind it.
Try EurekaThe disclosed technology relates to a working fluid for a low global warming potential (GWP) refrigeration system that includes a compressor, where the working fluid includes an ester based lubricant and a low GWP refrigerant, and where the ester based lubricant includes an ester of one or more branched carboxylic acids where said branched carboxylic acid contains 8 or less carbon atoms. The disclosed technology provides commercially useful low GWP working fluids that do not have the solubility and/or miscibility problems commonly seen in low GWP fluids, including high viscosity fluids and applications.Filed by The Lubrizol Corporation, published 2017-01-05.
View full filing| # | Publication no. | Patent title | Citations |
|---|---|---|---|
| 1 | US6575716B1 | Linear compressor | 37 |
| 2 | WO2000032934A1 | Linear compressor | 24 |
| 3 | US20230130167A1 | Climate control systems for use with high glide working fluids and methods for operation thereof | 23 |
| 4 | WO2019023267A1 | Refrigerant composition measurement system | 16 |
| 5 | US20160009974A1 | Working Fluids Comprising Fluorinated Olefins / Fluorinated Saturated Hydrocarbon Blends and Polyol Esters | 13 |
| 6 | WO2017184975A1 | Refrigerant compositions and low global-warming-potential blends | 12 |
| 7 | JP2011027374A | Expansion valve | 12 |
| 8 | US20160312095A1 | Refrigerant compositions | 9 |
| 9 | JP2010265777A | compressor | 9 |
| 10 | WO2023069273A1 | Climate control systems for use with high glide working fluids and methods for operation thereof | 8 |
Citation counts reflect influence within this searched corpus and skew toward older filings; they are not a measure of current commercial relevance.
Each row carries its publication number; clicking a row searches Eureka by that number.
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The agent works the prompt against patents and technical literature, citing every source.
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Browse MCP servers →Three patterns stand out once the filing trend, IPC split and citation table are read together.
The 2018 peak of 43 records lines up with regulatory phase-down pressure on high-GWP HFCs; the fall to 7 by 2022 suggests the initial claim space around drop-in blends and flammability classification was staked out early and has not attracted a second wave of filers.
A third of the dataset touches lubricant chemistry or lubricant property indices, meaning a refrigerant blend claim frequently carries dependent claims on the ester lubricant it must run with. Freedom-to-operate work on a new blend cannot stop at the refrigerant composition itself.
The two highest-cited records in the corpus are linear compressor patents rather than refrigerant compositions, indicating that mechanical system design around new working fluids has drawn more downstream citation traffic than the chemistry itself.
Eureka can read the same corpus for gaps instead of for coverage: under-claimed branches adjacent to low-gwp refrigerants, with the prior art for and against each one.
Receiving-office data shows the United States (40), Europe (22) and Japan (19) as the primary filing venues, with WIPO PCT filings (17) indicating multi-jurisdiction strategies among a subset of assignees. China (8) and India (8) trail well behind.
Every assignee tracked for recent-year momentum, including established refrigerant and lubricant specialists, shows zero filings in the latest year and flat-to-negative year-over-year change. This is consistent with the broader post-2018 decline rather than any single company exiting the space.
The United States, European Patent Office and Japan account for the bulk of receiving-office activity, with WIPO PCT filings suggesting a smaller group of assignees pursuing coordinated multi-country protection rather than single-market filing.
Only seven co-assignee pairs appear across 154 families, and the strongest pairing links two related Mitsubishi Electric entities. This is a landscape of largely independent filers rather than joint-venture or cross-licensing patterns.
| Assignee | Recent year | YoY |
|---|---|---|
| The Chemours Company FC, LLC | 0 | -100% |
| RPL Holdings Limited | 0 | — |
| The Lubrizol Corporation | 0 | — |
| Trane International Inc. | 0 | — |
| Fujitsu General Limited | 0 | — |
| Chemtura Corporation | 0 | — |
| Panasonic Corporation (Japan) | 0 | — |
| Mitsubishi Electric Corporation | 0 | — |
The dataset points to a mature but stalled filing wave with a few technically specific gaps still open. These are reasonable next steps depending on whether the goal is freedom-to-operate, whitespace filing, or monitoring.
Given that half the dataset ties lubricant compatibility to the refrigerant composition, any new blend should be checked against C10M/C10N claim language, not just C09K refrigerant composition claims.
Explore lubricant-compatibility claims in EurekaUS20230130167A1 signals active interest in climate control systems for high-glide fluids; the surrounding claim space appears thinner than the core drop-in-replacement cluster.
Search high-glide working fluid filings in EurekaWith every tracked assignee flat or declining, a renewed regulatory trigger is the most likely cause of the next uptick — worth setting an alert rather than assuming the space is closed.
Set up assignee monitoring in EurekaThe dataset shows filing activity spread across a set of refrigerant chemical companies and HVAC/compressor manufacturers rather than a single dominant holder. No assignee shows positive momentum in the most recent tracked year, and several well-known lubricant and refrigerant specialists have dropped to zero recent filings. This suggests the early claim positions were staked out during the 2017-2019 filing wave and have not been meaningfully contested since.
Filings rose to 43 records in 2018, likely reflecting a rush to claim drop-in replacement compositions and system adaptations ahead of regulatory phase-down deadlines for high-GWP HFCs. The subsequent decline to a midpoint of 7 filings by 2022 indicates that the initial wave of assignees secured their core claims early rather than a market that continued expanding. Publication lag of about 18 months means the very latest years in any such trend will always look thinner than they eventually turn out to be, but a multi-year decline visible well before the cut-off is not fully explained by lag alone.
In this corpus, drop-in replacement claims typically focus on matching the performance envelope, flammability class and lubricant compatibility of an existing refrigerant so that equipment does not need redesign, while new blend claims focus on the composition itself. Many records combine both: a composition claim paired with dependent claims on system efficiency or lubricant miscibility. This is why C10M and C10N lubricant-related IPC codes appear in roughly a third of the dataset rather than sitting in a separate lubricant-only silo.
High filing density in a subclass like C09K means that particular claim space is occupied, not that the underlying technology has stopped developing. The steep decline after 2018 is more consistent with the core drop-in-replacement and flammability-classification claims being staked early, leaving narrower technical niches, such as high-glide working fluids or vehicle-specific A/C integration, comparatively open. A new regulatory trigger or a technical breakthrough in blend chemistry could still restart filing activity.
Based on IPC composition, the thinnest represented areas relative to the core C09K and F25B clusters are air-conditioning-specific system integration (F24F, 4 records), positive-displacement pump compatibility (F04B, 5 records) and refrigerator-specific cooling applications (F25D, 6 records). The high-glide working fluid climate control approach referenced in recent filings also appears to sit in a less crowded part of the landscape than the core drop-in-replacement claims. These are reasonable starting points for a narrower novelty search before drafting new claims.
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Disclaimer. This page is generated from Patsnap Eureka data drawn from a limited snapshot of global patent and scientific-literature records, and is provided for general information and reference only.
Patent data carries inherent limitations: recent filings (typically the most recent 18–24 months) are under-counted due to standard publication lag; counts may be reported at either a patent-family or a patent-record basis and are not always directly comparable; classification, applicant-name, and citation data may contain errors, duplicates, or omissions; and the underlying search query defines and constrains the scope shown. As a result, the analysis may be incomplete or inaccurate and may not reflect the full technology landscape.
Nothing on this page constitutes an exhaustive prior-art, novelty, freedom-to-operate, or validity search, nor does it constitute legal, financial, investment, or professional advice, and it should not be relied upon as such. Any patent, commercial, or strategic decision should be verified independently and reviewed with qualified patent, legal, and domain professionals. Patsnap makes no warranties, express or implied, as to the accuracy, completeness, or fitness for any particular purpose of the information presented.
Machine translation. Assignee and organisation names originally recorded in Chinese, Japanese or Korean have been rendered into English by an AI translation step so that the tables stay readable. These renderings are best-effort and may not match a company's registered English name; the original name is what the underlying patent record carries, and it is what any Eureka query launched from this page uses.