Maleic Anhydride Grafted Polyolefins Patents: Top Companies & Trends 2026
- 642 patent families span 2015 through mid-2026, with China (226 filings) now the leading receiving office ahead of the United States (134) and EPO (88).
- Filing has plateaued, not grown, since the 2022 midpoint of 22 — activity peaked at 45 in 2025 after starting at 35 in 2017.
- Compositions and adhesives dominate the classification mix, while coatings (81 records) and shaping (76) trail furthest behind, marking where claim space is thinnest.
Filing growth compares 2021 (11 records) with 2024 (14) — a three-year span. 2024 is the most recent year we treat as complete: publication lags filing by roughly 18 months, so 2025 onwards are still filling in and any growth rate that ends there would understate the field. Top-5 share is the combined record count of the five largest assignees divided by all 642 records in scope (CR5), not by the ranked leaders only.
A mature compatibilizer chemistry with a shifting filing map
Maleic anhydride grafted polyolefins are made by reacting polyethylene or polypropylene with maleic anhydride, usually under peroxide initiation in a reactive extrusion process, to attach a small but functionally critical fraction of anhydride groups onto the polymer backbone. That functionality lets an otherwise nonpolar polyolefin bond to polar materials — nylon, polyester, PLA, glass fibre, metal — making the grafted polymer valuable as a compatibilizer in blends, as an adhesive tie layer in multilayer film, and as a coupling agent in filled composites. Patent claims in this space tend to hinge on narrow, testable parameters: grafting degree, initiator level, and processing conditions, rather than on the base chemistry, which has been public for decades.
The 642 families tracked here run from 2015 through the mid-2026 data cut-off, concentrated heavily in composition and additive classifications rather than end-use application classes, and increasingly filed through Chinese receiving offices.
Filing trends and technology composition
The dataset spans 642 published patent families from 2015 through the 2026 cut-off, filed against a search string targeting maleic-anhydride grafting, reactive extrusion and compatibilizer claims.
Filing activity has plateaued since 2022
Filings rose from 35 in 2017 to a peak of 45 in 2025, but the 2022 midpoint of 22 sits below both the start and the peak, and the partial 2026 count of 9 is consistent with normal publication lag rather than a real drop-off.
Compositions and adhesives dominate the classification mix
C08L polymer compositions (544 records) and C08F addition polymers (258) anchor the corpus, with C08K additives (251) close behind; adhesives (C09J, 127) and laminates (B32B, 76) form a smaller but distinct application cluster, while coatings (C09D, 81) and shaping (B29C, 76) trail furthest behind.
Shares are the percentage of the 642 records in scope. A patent can carry several IPC classes, so the shares add up to more than 100%.
Go deeper on Maleic Anhydride Grafted Polyolefins with Eureka
This page is one run against one query. Ask Eureka your own question about maleic anhydride grafted polyolefins and every answer comes back with the patent numbers behind it.
Try EurekaThe prior art shaping this claim space
US8362145B2 — Compatibilized polypropylene and polylactic acid blends and methods of making and using same
A composition comprising a blend of a polyolefin, polylactic acid, and a reactive modifier. A method of producing an oriented film comprising reactive extrusion compounding a mixture comprising polypropylene, polylactic acid, a reactive modifier to form a compatibilized polymeric blend, casting the compatibilized polymeric blend into a film, and orienting the film. A method of preparing a reactive modifier comprising contacting a polyolefin, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of an epoxy-functionalized polyolefin wherein the epoxy-functionalized polyolefin has a grafting yield of from 0.2 wt. % to 15 wt. %.Assignee: Fina Technology, Inc. · Granted 2013-01-29


| # | Publication no. | Patent title | Citations |
|---|---|---|---|
| 1 | US4517104A | Ethylene copolymer viscosity index improver-dispersant additive useful in oil compositions | 232 |
| 2 | US5709948A | Semi-interpenetrating polymer networks of epoxy and polyolefin resins, methods therefor, and uses thereof | 198 |
| 3 | US5843577A | Thermoplastic elastomers having improved surface properties | 108 |
| 4 | US4639495A | Extruding process for preparing functionalized polyolefin polymers | 108 |
| 5 | US20100143651A1 | Functionalized olefin polymers, compositions and articles prepared therefrom, and methods for making the same | 102 |
| 6 | US5387645A | Polyphthalamide composition | 102 |
| 7 | US20040220336A1 | Blend functionalized polyolefin adhesive | 96 |
| 8 | US7541402B2 | Blend functionalized polyolefin adhesive | 89 |
| 9 | US6503984B2 | TPE composition that exhibits excellent adhesion to textile fibers | 83 |
| 10 | US6093496A | Polyolefin containing polyetheramine modified functionalized polyolefin | 79 |
Citation counts favour older records within this searched corpus and should be read as a signal of influence, not current relevance.
Each row carries its publication number; clicking a row searches Eureka by that number.
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Browse MCP servers →What the filing pattern signals
Reading the classification split and filing trend together points to a technology area where the core chemistry is settled and competitive activity has shifted to narrower formulation and application claims.
Growth has flattened since the 2022 midpoint
Filings rose from 35 in 2017 to a peak of 45 in 2025, but the 2022 midpoint of 22 sits below both ends, showing an uneven rather than steadily rising filing rate. The partial 2026 count of 9 should not be read as a decline given normal publication lag.
Compositions and additive claims dominate over application claims
C08L polymer compositions (544) and C08F addition polymers (258) far outweigh application-specific subclasses like C09D coatings (81) and B29C shaping (76), indicating most claim activity centres on the compatibilizer chemistry itself rather than end-use formulations.
China has overtaken the US as the primary filing venue
China's 226 filings lead the United States (134) and EPO (88) by a wide margin, with WIPO PCT filings (61) trailing further, suggesting manufacturing-driven filing strategy has shifted toward Chinese domestic protection.
Ownership is consolidated with limited cross-institutional filing
Only ten co-assignee pairs appear across the corpus, the strongest being Dow Global Technologies with Rohm and Haas (16 shared families), pointing to filing being handled mostly within single corporate groups rather than joint ventures.
Eureka can read the same corpus for gaps instead of for coverage: under-claimed branches adjacent to maleic anhydride grafted polyolefins, with the prior art for and against each one.
Who is active, and who has slowed down
Recent-year filing momentum across nearly every tracked assignee has dropped to zero or near-zero, which is consistent with a chemistry space that consolidated around a handful of large materials companies some years ago rather than one with new entrants actively filing today.
Dow Global Technologies remains the only assignee still filing
Among the tracked assignees, Dow Global Technologies is the only one showing any filing activity in the latest tracked year, with a single family, while every other listed assignee — including Eastman Chemical, Solvay and Becton Dickinson — shows zero.
Dow Global Technologies and Rohm and Haas file together most often
The strongest co-assignee relationship in the dataset links Dow Global Technologies with Rohm and Haas across sixteen shared families, with a second Dow-affiliated tie to Dow Silicones at eleven, suggesting internal cross-entity filing within the same corporate group rather than external collaboration.
One notable university collaboration stands out
Becton Dickinson and the University of Massachusetts share fourteen co-filed families, the largest academic-industry tie in the dataset, though Becton Dickinson itself shows no filings in the most recent tracked year.
| Assignee | Recent year | YoY |
|---|---|---|
| Dow Global Technologies | 1 | — |
| Huamei Longwei | 0 | -100% |
| Advanced Elastomer Systems, L.P. | 0 | — |
| Eastman Chemical Company | 0 | — |
| Solvay | 0 | — |
| Becton, Dickinson and Company | 0 | — |
| Rohm and Haas Company | 0 | — |
| University of Massachusetts | 0 | — |
Where to take this analysis next
The filing and classification data point to specific follow-up checks before committing to a formulation or a filing strategy in this space.
Run a freedom-to-operate check on the core grafting-yield claims
The most-cited records in this corpus carry specific numeric grafting-degree and process limitations; confirm whether a target formulation falls inside or outside those windows before scaling.
Check claim scope in EurekaTrack Dow's filing group for early signals
With most assignees showing zero recent-year filings, Dow Global Technologies and its co-filing entities are the clearest source of forward-looking activity to monitor.
Set up assignee monitoring in EurekaExplore the coatings and shaping white space
Classification density is thin in C09D and B29C relative to the core compatibilizer clusters; a targeted search there may surface filing opportunities before the space fills in.
Search white space in EurekaCommon questions on maleic anhydride grafted polyolefin patents
Most patents in this space use maleic-anhydride-grafted polyethylene or polypropylene as a compatibilizer, a reactive modifier that lets a nonpolar polyolefin bond chemically or adhere physically to a polar material such as nylon, PLA, a filler or a metal surface. The grafting reaction is typically run by reactive extrusion with a peroxide initiator, and claims are usually written around a specific grafting-degree or grafting-yield range rather than the chemistry alone. Adhesive tie-layers and laminate structures are the next largest application after general compatibilizer compositions, based on the C09J and B32B classification counts in this dataset.
Filing activity in this dataset is concentrated among a small group of large materials companies, with cross-filing ties visible in the co-assignee data — for example, Dow Global Technologies and Rohm and Haas share sixteen co-filed families, and Dow Global Technologies and Dow Silicones share eleven. Recent-year momentum across nearly every tracked assignee has slowed to zero or near-zero, which points to a mature, consolidated ownership structure rather than active new entrants. Readers should treat assignee names as filed, since patent office records often list corporate subsidiaries or predecessor entities rather than current parent brands.
The trend shows 45 filings in 2025 against only 9 recorded so far in 2026, but that drop is largely an artefact of publication lag: patent applications typically publish around eighteen months after filing, so the most recent one to two years in any filing trend will always look artificially low. The more meaningful signal is that the 2022 midpoint of 22 filings sits below both the 2017 starting point and the 2025 peak, indicating the underlying filing rate has been roughly flat with a bump rather than showing continuous growth. This pattern is typical of a technology area where the core compatibilizer chemistry is well established and filing now clusters around narrower formulation variants.
The classification data shows a clear density gap: compositions, adhesives and additive claims (C08L, C08F, C08K) are heavily filed, while coatings (C09D, 81 records) and plastics-shaping applications (B29C, 76) are comparatively thin. That gap suggests coating formulations that use a grafted polyolefin as the primary film-forming resin, rather than as a minor additive, are under-claimed relative to how mechanically compatible the chemistry is with that use. A first claim there would need a defined grafting-yield range plus a specified cure mechanism to differentiate from the existing compatibilizer art.
US8362145B2, assigned to Fina Technology and granted in 2013, claims a polypropylene/polylactic acid blend compatibilized using an epoxy-functionalized polyolefin reactive modifier made from a polyolefin, a multifunctional acrylate comonomer and an initiator, with a grafting yield specified between 0.2 and 15 weight percent. It is a narrow, chemistry-specific claim rather than a blanket claim over grafted polyolefins, so it mainly constrains work that combines that exact epoxy-acrylate grafting route with a PP/PLA blend. Formulators working with straight maleic-anhydride grafting chemistry, or with blends that do not involve polylactic acid, are generally outside its literal scope, though a full freedom-to-operate review of the claim language is still the safer route before commercial use.
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Disclaimer. This page is generated from Patsnap Eureka data drawn from a limited snapshot of global patent and scientific-literature records, and is provided for general information and reference only.
Patent data carries inherent limitations: recent filings (typically the most recent 18–24 months) are under-counted due to standard publication lag; counts may be reported at either a patent-family or a patent-record basis and are not always directly comparable; classification, applicant-name, and citation data may contain errors, duplicates, or omissions; and the underlying search query defines and constrains the scope shown. As a result, the analysis may be incomplete or inaccurate and may not reflect the full technology landscape.
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Machine translation. Assignee and organisation names originally recorded in Chinese, Japanese or Korean have been rendered into English by an AI translation step so that the tables stay readable. These renderings are best-effort and may not match a company’s registered English name; the original name is what the underlying patent record carries, and it is what any Eureka query launched from this page uses.