Membrane Reactor Catalyst Design Patents: Leaders & White Space 2026
- Filing has cooled from an 11-filing year in 2017 to single digits toward 2026, with a peak of 12 in 2024 — the field is active but not accelerating.
- B01J catalysis claims (177 records) dominate over pure separation claims (B01D, 130), meaning the catalyst-membrane interface, not the membrane alone, is where most claim activity sits.
- The most-cited prior art is two to three decades old, including a ceramic membrane patent cited 126 times, so current filers are building on a mature citation base rather than a fresh one.
What this landscape covers
Membrane reactor catalyst design sits at the intersection of separation science and heterogeneous catalysis: a single unit that both drives a chemical reaction and selectively separates a product, most often hydrogen, across a membrane. The patent record spans 208 families filed between 2015 and mid-2026, concentrated in B01J catalytic-process claims, B01D separation claims and C01B inorganic-compound claims — a signature of hydrogen and syngas production work. Ammonia cracking (C01C, 29 records), fuel cell integration (H01M, 42) and electrolytic production (C25B, 19) appear as secondary but non-trivial branches.
Filing offices skew toward the United States, China and WIPO PCT filings, with Europe, Australia and South Korea forming a second tier — evidence of a technology still being filed defensively across multiple jurisdictions rather than consolidated in one bloc.
Filing trend and technology composition
Annual filing counts and IPC subclass distribution for the 208 families in scope, drawn directly from the underlying dataset.
Filing activity, 2017–2026
Filings opened at 11 in 2017, moved through a midpoint of 5 in 2022, and peaked at 12 in 2024 before dropping toward 1 in the current partial year. Publication lag of roughly 18 months means the 2025-2026 figures will rise as later filings publish; treat the apparent decline at the very end of the series with caution.
IPC subclass distribution
B01J (catalysis) and B01D (separation) together account for the bulk of records, with C01B inorganic-compound claims close behind — consistent with hydrogen-focused membrane reactor work. Fuel cell (H01M) and electrolytic (C25B) subclasses show the technology's reach into adjacent energy applications.
Shares are the percentage of the 208 records in scope. A patent can carry several IPC classes, so the shares add up to more than 100%.
Go deeper on Membrane Reactor Catalyst Design with Eureka
This page is one run against one query. Ask Eureka your own question about membrane reactor catalyst design and every answer comes back with the patent numbers behind it.
Try EurekaMost-cited prior art and a representative recent filing
US11090628B2 — Catalytic membrane reactor for ammonia dehydrogenation
A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produce highly pure hydrogen from ammonia, and can operate for other chemical conversion processes. In one embodiment a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface impregnated with a metal catalyst such as ruthenium and plated with a hydrogen-permeable membrane such as palladium; an inner surface is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen.Filed by Colorado School of Mines, granted 2021-08-17.


| # | Publication no. | Patent title | Citations |
|---|---|---|---|
| 1 | US6146549A | Ceramic membranes for catalytic membrane reactors with high ionic conductivities and low expansion properties | 126 |
| 2 | US5366712A | Ceramic catalytic membrane reactor for the separation of hydrogen and/or isotopes thereof from fluid feeds | 75 |
| 3 | US20020022568A1 | Ceramic membranes for use in catalytic membrane reactors with high ionic conductivities and improved mechanic… | 71 |
| 4 | US6830596B1 | Electric power generation with heat exchanged membrane reactor (law 917) | 69 |
| 5 | WO1999021649A1 | Catalytic membrane reactor with two component three-dimensional catalysis | 52 |
| 6 | CN101597096A | 一种电催化膜反应器装置 | 48 |
| 7 | US5464798A | Ceramic-zeolite composite membranes and use for separation of vapor/gas mixtures | 46 |
| 8 | US5415891A | Method for forming metal-oxide-modified porous ceramic membranes | 44 |
| 9 | US6214757B1 | Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them | 42 |
| 10 | CN103596671A | 金属负载的二氧化硅基催化膜反应器组件 | 33 |
Citation counts reflect age as much as importance: the top-cited records here date back two to three decades and set the baseline that later filers design around or license past.
Patent titles are shown in the language they were filed in, not translated, so that each record stays verifiable against the original filing — a translated title will not match in Eureka or in any national register. Each row carries its publication number; clicking a row searches Eureka by that number.
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Browse MCP servers →What the numbers mean for a filing decision
Three patterns stand out once the raw counts are read against filing dates and citation age.
Catalyst-membrane interface is the crowded zone
B01J claims outnumber pure separation (B01D) claims by a wide margin, which means the contested ground is how the catalyst is deposited on, impregnated into or bonded to the membrane — not the membrane material itself. New entrants filing on membrane composition alone will run into less-crowded but also less-cited art.
Activity has plateaued, not accelerated
The trend moved from 11 filings in 2017 through a midpoint of 5 in 2022 to a peak of 12 in 2024. That is a flat-to-declining pattern over nearly a decade, not the steep ramp seen in fast-growing chemical technologies — useful context before assuming this is a land-grab field.
The influential art predates most current filers
The most-cited record in this set is a ceramic membrane patent that predates the current filing wave by decades. Current applicants are citing and designing around foundational ceramic and hydrogen-separation work rather than each other's recent filings, which suggests the core physics is settled and differentiation is happening at the manufacturing and integration level.
Eureka can read the same corpus for gaps instead of for coverage: under-claimed branches adjacent to membrane reactor catalyst design, with the prior art for and against each one.
Who is filing, and where the field is still open
Assignee activity is spread across national labs, universities, oil majors and specialist membrane companies, with several previously active filers showing no filings in the latest year.
Multiple established filers have gone quiet
Assignees including a Saudi oil major, an Italian energy research agency, a Dutch technical university and a Portuguese chemicals firm show zero filings in the most recent year despite earlier activity — either the work has shifted internal priority, moved to trade secret, or simply has not yet published under the 18-month lag.
Collaboration is narrow and specific
Only ten co-assignee pairs appear across 208 families, and the strongest is a national oil company paired with a university on five shared filings. This is a field of largely solo filers rather than dense joint-venture activity, which lowers the freedom-to-operate risk from tangled joint ownership.
No single office dominates filing strategy
The United States, China and WIPO PCT filings sit within a few records of each other, with Europe close behind. Filers are not concentrating protection in one jurisdiction, which points to an expectation of commercial deployment across multiple regions rather than a single home market.
| Assignee | Recent year | YoY |
|---|---|---|
| Eltron Research Inc. | 0 | — |
| CUF – Companhia Uniao Fabril, Industrias Quimicas, S.A. | 0 | — |
| L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude | 0 | — |
| Saudi Arabian Oil Company (Saudi Aramco) | 0 | — |
| Italian National Agency for New Technologies, Energy and Sustainable Economic Development (ENEA) | 0 | — |
| Eindhoven University of Technology | 0 | — |
| Davy Systems Technology Company | 0 | — |
| Kustec Membrane Technology Co., Ltd. | 0 | — |
Where to take this next
The landscape points to a field with settled core physics and open manufacturing questions.
Map the catalyst-deposition sub-claims
Because B01J claims dominate over pure membrane-material claims, a freedom-to-operate check should focus on how catalysts are deposited, impregnated or bonded rather than on membrane composition alone.
Explore in EurekaWatch for republished 2025-2026 activity
The apparent drop-off in the last two years is very likely a publication-lag artefact rather than a real slowdown; revisit filing counts once later years catch up.
Track filings in EurekaCheck the quiet assignees for renewed activity
Several previously active filers show zero filings in the most recent year; a status check on their portfolios can reveal whether work moved to a subsidiary, a new co-filer, or trade secret.
Monitor assignees in EurekaCommon questions on membrane reactor catalyst patents
A membrane reactor catalyst is the active material that drives a chemical reaction — such as ammonia cracking or dehydrogenation — while integrated with or adjacent to a selectively permeable membrane inside the same unit. It is patented separately from the membrane because the claim scope differs: membrane claims typically cover material composition and pore structure, while catalyst-integration claims cover how the active metal is deposited, impregnated or bonded onto or into that structure. In this dataset, catalysis-subclass filings (B01J) substantially outnumber pure separation filings (B01D), showing that the catalyst-membrane interface is where most current claim activity sits.
Filers span national research institutes, universities, oil and gas majors, and specialist membrane manufacturers, with no single entity holding a dominant share of the 208 families reviewed. Co-filing is limited, with only ten identified co-assignee pairs, meaning most patents are filed solo rather than through joint ventures. Several previously active assignees, including energy research agencies and technical universities, show no filings in the most recent year, which may reflect a shift in priority, a move to trade secret protection, or simply publication lag.
The filing trend is flat to declining over the period reviewed: activity opened at 11 filings in 2017, passed through a midpoint of 5 in 2022, and peaked at 12 in 2024 before appearing to drop toward the most recent year. Because patent publication lags actual filing by roughly 18 months, the apparent decline in 2025-2026 almost certainly understates real activity and should firm up as later filings publish. Read the multi-year plateau, not the final data point, as the more reliable signal of overall momentum.
US11090628B2, assigned to Colorado School of Mines, claims a catalytic membrane reactor built on a tubular yttria-stabilized zirconia ceramic support, with a ruthenium catalyst impregnated on the outer surface, a palladium hydrogen-permeable membrane plated over it, and cesium impregnated on the inner surface to promote ammonia conversion to hydrogen and nitrogen. It blocks that specific combination of support material, catalyst metal, membrane metal and promoter for ammonia dehydrogenation, rather than catalytic membrane reactors generally. Designs using different support ceramics, different catalyst or promoter metals, or a different membrane material would likely sit outside its literal claim scope, though a full freedom-to-operate review should check dependent claims and file history.
The clearest gaps sit in sub-areas with filing activity but comparatively thin claim density relative to the core catalyst-membrane interface: cesium-promoted ammonia-cracking supports, electrolytic membrane-catalyst co-integration overlapping with C25B, transfer of ceramic membrane designs into fuel cell architectures, and structured catalyst coatings on non-palladium membranes. These branches show enough activity to confirm commercial interest but not enough dense prior art to make new claims immediately blocked. A first claim in one of these areas would need to specify the support material, the catalyst-deposition method and the target reaction to distinguish it from the foundational ceramic-membrane art that already dominates citations.
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Disclaimer. This page is generated from Patsnap Eureka data drawn from a limited snapshot of global patent and scientific-literature records, and is provided for general information and reference only.
Patent data carries inherent limitations: recent filings (typically the most recent 18–24 months) are under-counted due to standard publication lag; counts may be reported at either a patent-family or a patent-record basis and are not always directly comparable; classification, applicant-name, and citation data may contain errors, duplicates, or omissions; and the underlying search query defines and constrains the scope shown. As a result, the analysis may be incomplete or inaccurate and may not reflect the full technology landscape.
Nothing on this page constitutes an exhaustive prior-art, novelty, freedom-to-operate, or validity search, nor does it constitute legal, financial, investment, or professional advice, and it should not be relied upon as such. Any patent, commercial, or strategic decision should be verified independently and reviewed with qualified patent, legal, and domain professionals. Patsnap makes no warranties, express or implied, as to the accuracy, completeness, or fitness for any particular purpose of the information presented.
Machine translation. Assignee and organisation names originally recorded in Chinese, Japanese or Korean have been rendered into English by an AI translation step so that the tables stay readable. These renderings are best-effort and may not match a company’s registered English name; the original name is what the underlying patent record carries, and it is what any Eureka query launched from this page uses.