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The agent works the prompt against patents and technical literature, citing every source.
Run your analysis now →Filing growth compares 2021 (307 records) with 2024 (226) — a three-year span. 2024 is the most recent year we treat as complete: publication lags filing by roughly 18 months, so 2025 onwards are still filling in and any growth rate that ends there would understate the field. Top-5 share is the combined record count of the five largest assignees divided by all 15,742 records in scope (CR5), not by the ranked leaders only.
This dataset tracks patent activity at the intersection of methanol-to-olefins (MTO) and methanol-to-gasoline (MTG) conversion routes, built around zeolite catalyst chemistry and the operational problems that determine whether a plant runs economically: coke deposition, catalyst regeneration, fluidized-bed heat removal, and the propylene-to-ethylene ratio a given process delivers. It spans 15,742 published records filed between 2015 and mid-2026.
The search logic pairs core conversion-route terms with the operational and reactor-engineering language that separates a lab-scale zeolite claim from a commercially defensible process claim. That combination is deliberate: a catalyst composition claim without a fluidized-bed or regeneration limitation is a different, much larger prior-art space than the one mapped here.
Pick a task. Every answer cites the patents behind it.
Two views of the same 15,742-record corpus: how filing activity has moved year over year, and which IPC subclasses carry the claim density.
Annual filings ran as high as 572 in 2017, the peak year in the dataset. Between 2021 and 2024 — the most recent span with reliable, largely-published figures — filings dropped 26%, from 307 to 226. Counts for 2025 and 2026 are shown but should be read as partial: publication typically lags filing by around 18 months, so recent-year totals will rise as more records surface.
C07C (acyclic and carbocyclic compounds) appears on 54.6% of records and B01J (catalytic processes) on 50.7%, with C10G (hydrocarbon oil refining) close behind at 45.9% — the three subclasses a filer must search first. Everything else, including separation processes (B01D, 3.6%) and coke/destructive distillation (C10B, 3.0%), is comparatively thin, which is where narrower claims are more likely to clear.
Shares are the percentage of the 15,742 records in scope. A patent can carry several IPC classes, so the shares add up to more than 100%.
This page is one run against one query. Ask Eureka your own question about methanol to olefins and chemicals and every answer comes back with the patent numbers behind it.
Try EurekaFiled by China Petroleum & Chemical Corporation and published December 2024, this patent claims a fluidized-bed methanol-to-olefins process that controls temperature differences within specific concentration bands across separate dilute-phase and dense-phase zones of the reactor, targeting tighter heat management during methanol conversion to ethylene and propylene.Reactor-zone temperature control, not catalyst composition, is the claim's core limitation.
View full record| # | Publication no. | Patent title | Citations |
|---|---|---|---|
| 1 | US6166282A | Fast-fluidized bed reactor for MTO process | 1,013 |
| 2 | US4556477A | Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks | 549 |
| 3 | US20100030002A1 | Ethylene production from acetic acid utilizing dual reaction zone process | 432 |
| 4 | US3751504A | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation | 427 |
| 5 | US20100197485A1 | Catalysts for making ethanol from acetic acid | 379 |
| 6 | US5053373A | Zeolite SSZ-32 | 374 |
| 7 | US6538169B1 | FCC process with improved yield of light olefins | 350 |
| 8 | US5510306A | Process for isomerizing linear olefins to isoolefins | 330 |
| 9 | US4300009A | Conversion of biological material to liquid fuels | 309 |
| 10 | US6162415A | Synthesis of SAPO-44 | 287 |
Citation counts accumulate over time, so older filings such as the 1985 ZSM-22 patent naturally lead — treat this as a map of influence, not of current commercial relevance.
Each row carries its publication number; clicking a row searches Eureka by that number.
When you want the answer in the next five minutes.
The agent works the prompt against patents and technical literature, citing every source.
Run your analysis now →When it has to run inside your own pipeline.
Patent search, landscape analysis and assignee resolution as MCP tools. Drop them into any agent framework, or call REST directly.
Browse MCP servers →Three read-outs from the numbers above, framed for a filing or freedom-to-operate decision rather than as trivia.
With the top five assignees combined controlling over a third of all records, and the top ten reaching 46.5%, new entrants working on core zeolite-catalyst or fluidized-bed claims are filing into occupied territory rather than open ground.
Filing volume peaked at 572 records in 2017 and has since declined through the most recent complete filing years. That decline should not be read as the field closing — it more likely reflects a maturing set of core claims rather than falling commercial interest in MTO/MTG routes.
Despite coke deposition being a named search term, only 473 records — 3.0% of the corpus — sit in the C10B subclass, versus over half the corpus in core conversion-chemistry classes. That gap is a candidate area for narrower process claims.
Eureka can read the same corpus for gaps instead of for coverage: under-claimed branches adjacent to methanol to olefins and chemicals, with the prior art for and against each one.
The ranked leaders account for a large share of filings, but momentum in the most recent year has slowed even among the largest historical filers — a signal that the core claim territory is largely staked out.
The leading assignee's count is roughly three times the fifth-place total of 585, and more than five times tenth place at 292 — a steep drop-off rather than a gradual one.
Assignees with large historical portfolios show sharply reduced or zero filings in the latest year — a pattern consistent with a field where core process claims were staked years ago and current activity is incremental.
The strongest co-assignee pair in the dataset spans dozens of shared filings, pointing to sustained joint development programmes rather than one-off collaborations, particularly around catalyst and reactor engineering claims.
| Assignee | Recent year | YoY |
|---|---|---|
| ExxonMobil Technology and Engineering Company | 2 | -67% |
| UOP LLC | 1 | -75% |
| Mobil Oil Corporation | 0 | — |
| ExxonMobil Chemical Patents Inc. | 0 | — |
| Celanese International Corporation | 0 | — |
| Shell Internationale Research Maatschappij B.V. | 0 | — |
| Chevron U.S.A. Inc. | 0 | -100% |
| Fina Technology, Inc. | 0 | — |
The landscape numbers point to where claim density sits and where it doesn't; the next step is testing a specific claim or design-around against the underlying records.
Run a targeted search against the fluidized-bed and heat-removal claims held by the leading assignees before committing engineering resources to a reactor configuration.
Explore in EurekaCoke-handling and separation-process claims are comparatively thin today; monitoring filing activity there over the next few publication cycles will show whether that gap is closing.
Set up monitoring in EurekaThe assignee ranking is led by one company holding 1,753 of the 15,742 records in scope, well ahead of the fifth-ranked assignee at 585. The top five assignees combined account for 35.1% of all records, and the top ten reach 46.5%, so filing activity is concentrated among a small group of legacy petrochemical and catalyst companies rather than spread evenly across the field. Anyone evaluating freedom to operate should start with these leaders' portfolios before looking at the long tail of single-filing entrants.
Filings peaked in 2017 at 572 records and declined to 226 by 2024, a 26% drop across that span using the most recent years with reliable, largely-published data. Figures for 2025 and 2026 appear lower still, but that reflects publication lag of roughly 18 months rather than an actual collapse in filing. The honest read is that the field has cooled from its 2017 peak, not that it has stopped.
Both routes start from methanol over a zeolite catalyst, but MTO claims target ethylene and propylene yield and typically hinge on reactor conditions like fluidized-bed heat removal and the propylene-to-ethylene ratio, while MTG claims target gasoline-range hydrocarbons and lean more on catalyst shape-selectivity and pore geometry. This dataset captures both routes because the underlying reactor-engineering and catalyst-regeneration problems overlap heavily between them. A given company's portfolio often spans both if it operates across fuel and chemical product lines.
Coke and destructive-distillation classification (C10B) appears on only 3.0% of the 15,742 records, and separation-process claims (B01D) sit at 3.6%, both well below the 50%-plus density seen in core conversion-chemistry and catalysis classes. That gap suggests coke-selective regeneration cycles and downstream separation-train integration are comparatively under-claimed relative to the core catalyst and reactor claims. It does not mean these areas are unimportant — coke deposition is a named search term in this dataset — only that fewer patents have staked specific claims there.
Not necessarily. The most-cited record in this dataset, covering a fast-fluidized-bed MTO reactor, has accumulated over a thousand citations, but citation counts build up over time within a searched corpus and therefore favour older filings regardless of current commercial relevance. A 2024 filing on reactor-zone temperature control, for example, has had far less time to accumulate citations even if its claims are more directly relevant to current plant design. Citation count is best read as a signal of historical influence, not of present-day importance.
Go past this page: query the whole methanol to olefins and chemicals corpus yourself, in your own scope.
Every answer comes back with patent numbers you can open.
Disclaimer. This page is generated from Patsnap Eureka data drawn from a limited snapshot of global patent and scientific-literature records, and is provided for general information and reference only.
Patent data carries inherent limitations: recent filings (typically the most recent 18–24 months) are under-counted due to standard publication lag; counts may be reported at either a patent-family or a patent-record basis and are not always directly comparable; classification, applicant-name, and citation data may contain errors, duplicates, or omissions; and the underlying search query defines and constrains the scope shown. As a result, the analysis may be incomplete or inaccurate and may not reflect the full technology landscape.
Nothing on this page constitutes an exhaustive prior-art, novelty, freedom-to-operate, or validity search, nor does it constitute legal, financial, investment, or professional advice, and it should not be relied upon as such. Any patent, commercial, or strategic decision should be verified independently and reviewed with qualified patent, legal, and domain professionals. Patsnap makes no warranties, express or implied, as to the accuracy, completeness, or fitness for any particular purpose of the information presented.
Machine translation. Assignee and organisation names originally recorded in Chinese, Japanese or Korean have been rendered into English by an AI translation step so that the tables stay readable. These renderings are best-effort and may not match a company's registered English name; the original name is what the underlying patent record carries, and it is what any Eureka query launched from this page uses.
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