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Photoresist Underlayer & Hardmask Patents: Leaders, Trends 2026

Photoresist Underlayer & Hardmask Patents: Leaders, Trends 2026
https://www.patsnap.com/resources/blog/rd-blog/semiconductor-photoresist-underlayers-and-hardmasks-patent-landscape/ · Patsnap · data cut-off 2026-07-31 · downloaded from the live page
Patent Landscape · Semiconductors
Semiconductor photoresist underlayer and hardmask patents: who is still filing
  • Filing has cooled since its 2024 peak. 108 families published that year against 57 in 2017, but the two most recent full years show growth flattening rather than accelerating.
  • Momentum has swung to near zero across the largest holders. Several of the biggest assignees, including Shin-Etsu, JSR and Samsung SDI, show 0 filings and -100% year-on-year in the latest data.
  • Claims cluster tightly in photolithography and polymer chemistry. G03F and H01L together dominate the IPC mix, while C07F organometallic chemistry sits far behind at only 73 records.
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1,282
Published Records
78%
Top-5 Share of All Records
+17%
Filing Growth 2021→2024
US
Leading Jurisdiction

Filing growth compares 2021 (92 records) with 2024 (108) — a three-year span. 2024 is the most recent year we treat as complete: publication lags filing by roughly 18 months, so 2025 onwards are still filling in and any growth rate that ends there would understate the field. Top-5 share is the combined record count of the five largest assignees divided by all 1,282 records in scope (CR5), not by the ranked leaders only.

Published byPatsnap Research··7 min readSourced from Patsnap Eureka
Overview

What this landscape covers

This landscape tracks patent families addressing hardmask materials, spin-on carbon and resist underlayer chemistries, filtered to documents that make specific claims around etch selectivity, planarization, outgassing, pattern collapse or adhesion. The scope spans IPC classes H01L21, G03F7 and C08G61, capturing both the semiconductor-process side and the underlying polymer chemistry.

Coverage runs from 2015 through the 2026 data cut-off. Because publication typically lags filing by around 18 months, the last one to two years in any trend chart will always look thinner than the underlying filing activity actually was.

Filing activity, 2017-2026
  1. 1NISSAN CHEM CORP532
  2. 2SHIN ETSU CHEMICAL CO LTD265
  3. 3JSR CORPORATION104
  4. 4SAMSUNG SDI CO LTD62
  5. 5INTERNATIONAL BUSINESS MACHINE CORPORATION36
  6. 6APPLIED MATERIALS INC36
  7. 7INTEL CORP33
  8. 8CHEIL INDUSTRIES INC31
  9. 9TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD22
  10. 10MITSUBISHI GAS CHEM CO INC18
Source: Patsnap Eureka. Assignee ranking and totals. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP

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The numbers

Filing trend and technology composition

1,282 patent families sit in this dataset, drawn overwhelmingly from US, European and Taiwanese filings, with meaningful activity in WIPO, Japan and China.

A peak in 2024, then a pullback

Filings rose from 57 in 2017 to a peak of 108 in 2024, passing through 83 at the 2022 midpoint. The trajectory is flat-to-declining rather than a steady climb, consistent with a technology where core claim space is already well occupied.

A peak in 2024, then a pullback03060901205720172018201920202021202220231082024202522026Most recent year is partial — publication lag means later filings are not yet visible.

Photolithography and semiconductor devices dominate

G03F (1,059 records) and H01L (789) anchor the dataset, with C08G condensation-polymer chemistry a distant third at 417. C09D coatings and C08L polymer compositions form a mid tier, while C08F addition polymers and C07F organometallic chemistry sit at the thin edge of the distribution — a signal of where formulation-level claims are sparser.

Photolithography and semiconductor devices dominateG03F · Photolithography & photomechan…1,05982.6%H01L · Semiconductor devices78961.5%C08G · Condensation polymers41732.5%H10P31124.3%C09D · Coatings, paints & inks28622.3%C08L · Polymer compositions1159.0%C08F · Addition polymers (vinyl etc.)977.6%C07F · Organo-metallic & non-carbon c…735.7%Other28021.8%

Shares are the percentage of the 1,282 records in scope. A patent can carry several IPC classes, so the shares add up to more than 100%.

Source: Patsnap Eureka. Filing trend and technology composition. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.

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Key patents

The documents shaping this space

Representative filing
US20160147152A12016-05-26

Additive for resist underlayer film-forming composition and resist underlayer film-forming composition containing the same

NISSAN CHEMICAL INDUSTRIES, LTD.

The filing describes an additive that modifies the surface state of a resist underlayer film into a hydrophobic condition, intended to improve adhesion between the underlayer and the resist pattern formed on top of it. The additive is a polymer built from a defined structural unit combining an aliphatic, alicyclic or heterocyclic group with a linking group.Filed by Nissan Chemical Industries, published 2016-05-26.

US20160147152A1 — patent drawing 1US20160147152A1 — patent drawing 2
View full filing
Most-cited records in the dataset
#Publication no.Patent titleCitations
1US9916980B1Method of forming a structure on a substrate483
2WO2018109554A1Method of forming a structure on a substrate463
3US20060003182A1Method for forming controlled geometry hardmasks including subresolution elements and resulting structures175
4JP2008158002AComposition for resist underlayer film, and its manufacturing method152
5US5240878AMethod for forming patterned films on a substrate141
6US20090208880A1Process sequence for formation of patterned hard mask film (RFP) without need for photoresist or dry etch105
7US6492222B1Method of dry etching PZT capacitor stack to form high-density ferroelectric memory devices91
8WO2010061774A1Composition for forming resist underlayer film with reduced outgassing85
9WO2006093057A1Composition for underlayer film of resist and process for producing the same84
10US20090311624A1Resist underlayer film forming composition containing liquid additive80

Citation counts reflect influence within the searched corpus and favour older filings; treat them as a map of prior art density, not a ranking of current importance.

Each row carries its publication number; clicking a row searches Eureka by that number.

Source: Patsnap Eureka. Citation counts and representative records. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
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Insights

What the filing pattern tells you

Reading the trend and the IPC mix together points to a field where the chemistry claims are dense but the filing pace itself has stopped accelerating.

Trend
108 in 2024, 2 in 2026
peak vs. latest partial year

Growth has plateaued

The climb from 57 filings in 2017 to a 2024 peak of 108 was not sustained; the 2026 figure is a partial year, but the two years either side of the peak already show flattening, not fresh acceleration.

Publication lag means the true 2025-2026 picture will firm up over the next 12-18 months.
Composition
1,059 in G03F
vs. 73 in C07F

Claims concentrate in lithography chemistry

G03F photolithography and H01L semiconductor-device claims dominate the corpus. Organometallic chemistry (C07F) and vinyl-type addition polymers (C08F) trail well behind, suggesting formulation routes outside mainstream condensation polymers are comparatively under-claimed.

IPC counts overlap where a single family spans multiple subclasses.
Momentum
-100% YoY
at several major holders

The largest assignees have gone quiet

Shin-Etsu, JSR, Samsung SDI, IBM and Applied Materials all show zero filings in the latest year, each a -100% swing from the prior year. Nissan Chemical is the one major holder still filing, though flat at 2.

A pullback across incumbents can mean saturation, a shift to trade secret, or a lull ahead of the next design cycle.
Geography
743 US receiving-office filings
vs. 58 in China

Filing activity still centres on the US

The United States receives more than four times the filings of the next-largest office (Europe, 171), with Taiwan, WIPO, Japan and China each contributing a smaller, roughly comparable share.

Receiving-office counts reflect where protection was sought, not where R&D occurred.
Eureka AI Agent
Looking for what nobody has claimed yet?

Eureka can read the same corpus for gaps instead of for coverage: under-claimed branches adjacent to semiconductor photoresist underlayers and hardmasks, with the prior art for and against each one.

Find the white space →
Source: Patsnap Eureka. Co-assignee relationships and derived observations. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
Players

Who holds the ground, and who has stopped moving

The assignee list is long-tailed, with a handful of chemical and semiconductor majors accounting for the bulk of activity and most of that activity now cooling.

Momentum leader
2 filings, 0% YoY
latest year

Nissan Chemical is the one still filing

Among the assignees tracked for recent-year momentum, Nissan Chemical is the only one with filings in the latest year and flat rather than negative year-on-year change, a contrast to the near-total pullback elsewhere.

Flat momentum at a low base is not the same as growth.
Pullback
-100% YoY
across five major holders

Shin-Etsu, JSR, Samsung SDI, IBM and Applied Materials

Each of these shows zero filings in the latest year and a -100% year-on-year change, a pattern consistent across chemical suppliers and semiconductor-equipment makers alike rather than isolated to one sector.

Zero in the latest year may partly reflect publication lag rather than a stopped program.
Collaboration
10 co-assignee pairs
strongest tied to one Korean filer

Co-filing is limited and concentrated

Only 10 co-assignee pairs appear in the dataset, and the strongest links all involve the same Korean corporate filer paired with different named inventors, rather than cross-company joint filings.

Sparse co-assignment suggests most work here is filed solo rather than through formal partnerships.
🔍
Under-claimed branches worth a closer look
These sit at the thin edges of the IPC mix rather than the dense core.
organometallic hardmask precursors (C07F)vinyl addition-polymer underlayers (C08F)outgassing-suppression additive chemistrypattern-collapse mitigation coatings
Rank all filers by momentum →
Recent-year filing momentum by assignee
AssigneeRecent yearYoY
Nissan Chemical Corporation20%
Shin-Etsu Chemical Co., Ltd.0-100%
JSR Corporation0-100%
Samsung SDI Co., Ltd.0-100%
International Business Machines Corporation (IBM)0
Applied Materials, Inc.0-100%
Intel Corporation0
Taiwan Semiconductor Manufacturing Company (TSMC)0-100%
Source: Patsnap Eureka. Assignee-level momentum. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
What's next

Where to take this analysis

The trend and assignee data point to specific follow-up questions rather than a single conclusion.

Test freedom-to-operate against the cited core

The most-cited records, including US9916980B1 and its WO counterpart, sit at the centre of prior art for structure-forming methods; any new filing in that area should be checked against them first.

Explore claim charts

Watch whether incumbents resume filing

A -100% swing at five major holders in one year could mark saturation or a temporary lull; the next 12-18 months of publications will clarify which, given typical filing-to-publication lag.

Track assignee activity

Probe the thinner IPC branches

C07F and C08F carry far fewer records than G03F or H01L; that gap may reflect either limited technical viability or genuine white space worth testing with a first claim.

Run a white space search
Source: Patsnap Eureka. Forward-looking reading of the same dataset. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP
FAQ

Common questions about this landscape

Answers are grounded in the same dataset. Derived from a Patsnap search on Semiconductor Photoresist Underlayers and Hardmasks covering 2015–2026, data cut-off 2026-07-31. Counts reflect published records only and shift as new filings publish.Run this in Eureka MCP

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Disclaimer. This page is generated from Patsnap Eureka data drawn from a limited snapshot of global patent and scientific-literature records, and is provided for general information and reference only.

Patent data carries inherent limitations: recent filings (typically the most recent 18–24 months) are under-counted due to standard publication lag; counts may be reported at either a patent-family or a patent-record basis and are not always directly comparable; classification, applicant-name, and citation data may contain errors, duplicates, or omissions; and the underlying search query defines and constrains the scope shown. As a result, the analysis may be incomplete or inaccurate and may not reflect the full technology landscape.

Nothing on this page constitutes an exhaustive prior-art, novelty, freedom-to-operate, or validity search, nor does it constitute legal, financial, investment, or professional advice, and it should not be relied upon as such. Any patent, commercial, or strategic decision should be verified independently and reviewed with qualified patent, legal, and domain professionals. Patsnap makes no warranties, express or implied, as to the accuracy, completeness, or fitness for any particular purpose of the information presented.

Machine translation. Assignee and organisation names originally recorded in Chinese, Japanese or Korean have been rendered into English by an AI translation step so that the tables stay readable. These renderings are best-effort and may not match a company’s registered English name; the original name is what the underlying patent record carries, and it is what any Eureka query launched from this page uses.

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